Sulfur(IV)-mediated transformations: from ylide transfer to metal-free arylation of carbonyl compounds.
نویسندگان
چکیده
The development of a direct ylide transfer to carbonyl derivatives and of a sulfoxide-mediated arylation is presented from a unified perspective. Mechanistic studies (including density functional calculations) support a common reaction pathway and showcase how subtle changes in reactant properties can lead to disparate and seemingly unrelated reaction outcomes.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 135 19 شماره
صفحات -
تاریخ انتشار 2013